Callie Thorne on WHITE COLLAR (Photos) October 24, 2009 White Collar Matt Bomer as Neal Caffrey, Callie Thorne as Maria Fiametta Check out photos of Callie Thorne guest starring on the new USA series WHITE COLLAR episode 3 “Book of Hours” which airs Friday November 6 USA Network (10-11 p.m. ET). Callie Thorne will play Maria Fiametta who, based on these photos, does not seem to be a huge fan of Neal Caffrey (Matt Bomer). Thorne is better know as Sheila Keefe on the hit FX series Rescue Me. Episode Synopsis: WHITE COLLAR “Book of Hours” Episode 3 –To Be Published Watch White Collar Episodes Online now. Matt Bomer as Neal Caffrey, Callie Thorne as Maria Fiametta Share this:Click to share on Twitter (Opens in new window)Click to share on Facebook (Opens in new window)Click to share on Reddit (Opens in new window)Click to share on Google+ (Opens in new window)Click to share on Tumblr (Opens in new window)Click to share on Pocket (Opens in new window)